Not in the sheet itself, no, but you can download an offline copy of the historical match-up chart and perform any data analysis you want on it. Go to 'file' > 'download' > 'Excel' and you'll get an offline Excel file version. Then you can create a new tab and do whatever you want with it.
Most tournament wins will be either Zane or Troq, or possibly DeGrey, guaranteed. They're the most played characters with the highest percentage win rates.